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This paper presents advanced planar ZrO2 oxygen sensors being developed at Robert Bosch using a modified tetragonal partially stabilized zirconia (TZP) with high ionic conductivity, high phase stability and high thermo-mechanical strength. Green tape technology combined with highly automated thickfilm techniques allows robust and cost effective manufacturing of those novel sensing elements. Standardization of assembling parts reduces the complexity of the assembly line even in the case of different sensing principles. The sensor family meets the new requirements of modern ULEV strategies like fast light off below 10 s and linear control capability as well as high quality assurance standards. High volume production will start in 1997 for European customers.

Automotive catalysts close coupled to gasoline engines operated under high load are frequently subjected to bed temperatures well above 950 °C. Upon deceleration engine fuel cut is usually applied for the sake of fuel economy, robustness and driveability. Even though catalyst inlet gas temperatures drop down immediately after fuel cut - catalyst bed temperatures may rise significantly. Sources for catalyst temperature rise upon deceleration with fuel cut are discussed in this contribution.

A 1D+1D numerical model describing the ammonia based SCR process of NO and NO2 on vanadia-titania catalysts is presented. The model is able to simulate coated and extruded monoliths. Basing on a fundamental investigation of the catalytic processes a reaction mechanism for the NO/NO2 - NH3 reacting system is proposed and modeled. After the parameterization of the reaction mechanism the reaction kinetics have been coupled with models for heat and mass transport. Model validation has been performed with engine test bench experiments. Finally the model has been applied to study the influence of NO2 on SCR efficiency within ETC and ESC testcycles, Additional simulations have been conducted to identify the potential for catalyst volume reduction if NO2 is present in the inlet feed.

A two-dimensional numerical model describing the ammonia based SCR-process on vanadia-titania catalysts is presented. The model is able to simulate coated and extruded monoliths. For the determination of the intrinsic kinetics of the various NH3-NOx reactions, unsteady microreactor experiments were used. In order to account for the influence of transport effects the kinetics were coupled with a fully transient two-phase 1D+1D monolith channel model. The model has been validated extensively with laboratory data and engine test bench measurements. After validation the model has been applied to calculate catalyst NOx conversion maps, which were used to define catalyst sizes. Additional simulations were conducted studying the influence of cell density and NH3-dosage ratio.

The oil ash accumulation on modern three way catalyst (TWC) as well as its influence on catalyst deactivation is evaluated as a parameter of oil consumption, kind of oil additive compound and additive concentration. The oil ash accumulation is characterized by XRF and SEM/EDX in axial direction and into the washcoat depth of the catalyst. The deposition patterns of Ca, Mg, P and Zn are discussed. The catalytic activity of the vehicle and engine bench aged catalysts is measured by performing model gas tests and vehicle tests, respectively. The influence of oil ash accumulation on the lifetime emission behavior of the vehicle is discussed.

The usage of Electronic Diesel Control is increasing with todays stringent emissions regulations. This requirement also necessitates that such systems be versatile to meet the needs of the engine/vehicle manufacturer. EGR, start of injection, and fuel delivery can be electronically controlled. Depending on the design goals of the manufacturer any one or two of these can be controlled for partial and all of them for full Electronic Diesel Control. The development and application process has several critical areas. These include, development of the sensors, application of the different subsystems, failure warning and failure mode operation. All of these must be combined if design goals are to be met. As the capabilities of electronics increase it follows that electronic vehicle systems will also improve. Today impressive results have been achieved with systems that are in full or pilot production.

The background for the development activities of the motor vehicle industry is strongly influenced by lawmakers, with engine development, in particular, coming under increasing pressure from the requirements of emissions legislation. Demands for CO2 reduction and thus corresponding savings in consumption contrast with regulations which call for compliance with extremely low emission levels, featuring the extreme of zero tailpipe emissions, and alternative low emission levels which make accurate measurement a problem even with current analysis technology. An example of such requirements are the SULEV limits of California law. These standards have given rise to a wide variety of emission control concepts, each of which, however, has certain limitations in its application. In the context of this general setting, the paper shows that the phase directly subsequent to cold start should be focused upon if these ambitious targets are to be reached.

The improvement of DI diesel engines for passenger cars to fulfil pollutant emission limits and lower fuel consumption and noise is closely linked to continued development of the injection system. Today's injection systems demonstrate varying potential in terms of the flexibility of injection parameters for improving mixture formation and combustion. DaimlerChrysler evaluated the potential of different injection systems, looking particularly at the distributor pump, unit injection system and Common Rail system. Based on the results of these investigations, the Common Rail system was selected. The tests presented in this paper were performed on a single-cylinder engine with Common Rail system. They focused on increased rail pressure in combination with different nozzle geometries. The results show significant benefits in NOx/smoke trade off at part load conditions with high EGR rate.

In order to fulfill future emissions standards, there is a need for new exhaust-gas aftertreatment concepts, with NOx-emissions reduction in passenger car diesel engines being of particular importance. The NOx storage catalyst is one of the technologies currently under discussion with high NOx conversion potential, and which is under development at DaimlerChrysler for EURO IV standards. With this system, the nitrogen oxides contained in the diesel exhaust gas are stored under lean exhaust-gas conditions and are reduced in the catalyst through an enriched air-fuel ratio of the exhaust-gas and favorable thermal conditions. Hydrocarbons, carbon monoxide and hydrogen are used as reducing agents. DaimlerChrysler has analyzed the effect of sulphur contained in the fuel on the operation of various catalysts during laboratory and engine testing. The sulphur dioxide in the exhaust gas generates sulfates, which remain on the catalyst when nitrate compounds are regenerated briefly.

The present paper describes the results of a joint development program focussing on a system approach to meet the EURO IV emission standards for an upper class passenger car equipped with a newly developed high displacement gasoline engine. Based on the well known catalyst systems of recent V6- and V8-engines for the EURO III emission standards with a combination of close coupled catalysts and underfloor catalysts, the specific boundary conditions of an engine with an even larger engine displacement had to be considered. These boundary conditions consist of the space requirements in the engine compartment, the power/torque requirements and the cost requirements for the complete aftertreatment system. Theoretical studies and computer modeling showed essential improvements in catalyst performance by introducing thin wall substrates with low thermal inertia as well as high cell densities with increased geometric surface area.

The success of model-based ECU-functions relies on precise and efficient modeling of the behavior of combustion engines. Due to the limited computing power, usually a combination of physical models and calibration parameters is preferred for engine modeling in ECU. The parameters can be scalars, 1 or 2-dimensional empirical models, such as look-up table for volumetric efficiency and effective area of the exhaust gas recirculation (EGR). A novel algorithm is proposed to automatically calibrate the look-up tables characterizing stationary functional relationships in ECU-function of the air system of a diesel engine with minimum calibration cost. The algorithm runs in the framework of online design of experiment (DoE), in which Gaussian process model (GPM) is adopted to approximate the relationships of interest.

The spatial distribution of internal exhaust gas recirculation (EGR) is evaluated in an optically accessible direct injection spark ignition engine using near infrared laser absorption to visualize the distribution of the H2O molecule. The obtained overall internal exhaust gas recirculation compares well to gas-exchange cycle calculations and the spatial distributions are consistent with those measured with inverse LIF. The experimental procedures described in this report are designed to be simple and rapidly implemented without the need to resort to unusual optical components. The necessary spectral data of the selected absorption line is obtained from the HITEMP database and is validated with prior experiments carried out in a reference cell. Laser speckle in the images is effectively reduced using a ballistic diffuser.

Historically, whenever the automotive solutions’ state of art reaches a saturation level, the integration of new verticals of technology has always raised new opportunities to innovate, enhance and optimize automotive solutions. The predictive powertrain solutions using connectivity elements (e.g., navigation unit, e-Horizon or cloud-based services) are one of such areas of huge interest in automotive industry. The prior knowledge of trip destination and its route characteristics has potential to make prediction of powertrain modes or events in certain order and therefore it can add value in various application areas such as optimized energy management, lower fuel consumption, superior safety and comfort, etc.

The LEV II and SULEV/PZEV emission standards legislated by the US EPA and the Californian ARB will require continuous reduction in the vehicles' emission over the next several years. Similar requirements are under discussion in the European Union (EU) in the EU Stage V program. These future emission standards will require a more efficient after treatment device that exhibits high activity and excellent durabilty over an extended lifetime. The present study summarizes the findings of a joint development program targeting such demanding future emission challenges, which can only be met by a close and intensive co-operation of the individual expert teams. The use of active systems, e.g. HC-adsorber or electrically heated light-off catalysts, was not considered in this study. The following parameters were investigated in detail: The development of a high-tech three-way catalyst technology is described being tailored for applications on ultra thin wall ceramic substrates (UTWS).

Increasingly stringent tailpipe emissions regulations have prompted renewed interest in catalyst heating technology – where an integrated device supplies supplemental heat to accelerate catalyst ‘light-off’. Bosch and Boysen, following a collaborative multi-year effort, have developed a Rapid Catalyst Heating System (RCH) for gasoline-fueled applications. The RCH system provides upwards of 25 kW of thermal power, greatly enhancing catalyst performance and robustness. Additional benefits include reduction of precious metal loading (versus a ‘PGM-only’ approach) and avoidance of near-engine catalyst placement (limiting the need for enrichment strategies). The following paper provides a technical overview of the Bosch/Boysen (BOB) Rapid Catalyst Heating system – including a detailed review of the system’s architecture, key performance characteristics, and the associated impact on vehicle-level emissions.